Shimizu | Lancaster | Urbanski | Urbanski | Visser | Visser | Estes | |
name | German rockets | American rockets | Type-C model rocket engine |
||||
Black powder | 0-12 | ||||||
Sodium nitrate | 69 | ||||||
Potassium nitrate | 59-64 | 61 | 60 | 59 | 72 | 71.79 | |
Sulfur | 8-13 | 5 | 15 | 10 | 4 | 4 | 13.45 |
Charcoal, 150 mesh | 20-31 | 20 | 25 | 31 | 27 | 24 | 13.81 |
Charcoal, 40 mesh | 14 | ||||||
Dextrin | 0.95 |
Nitrate/sugar-based propellants
Candy propellant | Teleflite propellant | |
Potassium nitrate | 74.5 | 63 |
Sucrose | 25.5 | 27 |
Sulfur | 10 |
Composite ammonium perchlorate-based propellants
Visser | NASA | |
name | Shuttle booster rocket propellant |
|
Ammonium perchlorate | 80 | 69.9 |
Resin1 | 20 | |
Polybutadiene | 12.04 | |
Epoxy curing agent | 1.96 | |
Aluminum powder | 16 | |
Red iron oxide | 0.07 | |
Copper chromite | +1 |
1 - Epon 815 epoxy & curing agent U
Composite ammonium nitrate-based propellants
Urbanski | Urbanski | Visser | |
name | Oxidizing mix | AMT-2011 | |
Ammonium nitrate | 72 | 72.79 | 85-90 |
Sodium nitrate | 16 | ||
Ammonium dichromate | 8 | 1.99 | |
Ammonium chloride | 4 | ||
Urethane plastic | 10-15 | ||
Genpol A-20 polyester resin |
9.79 | ||
Methyl acrylate | 12.22 | ||
Styrene | 2.22 | ||
Methyl ethyl ketone | 0.49 | ||
Cobalt octanoate (1% in styrene) |
0.25 | ||
Lecithin (10% in styrene) |
0.25 |
Composite potassium perchlorate-based propellants
Zaehringer | Altermann and Katchalsky |
Altermann and Katchalsky |
Altermann and Katchalsky |
Altermann and Katchalsky |
|
name | Galcit Alt 161 | Aeroplex K I | Aeroplex K II | Aeroplex K III | Aeroplex K IV |
Potassium perchlorate | 75 | 80 | 77.5 | 75 | 70 |
Asphalt with mineral oil or resin |
25 | ||||
Methyl polymethacrylate | 20 | 22.5 | 25 | 30 |
NOTE: These propellants are based on polyethylene sulfide rubbers mixed with ammonium perchlorate. According to the Thiokol Cehmical Corporation, liquid thiokol is produced by condensing ethylene chlorohydrin to dichlorodiethylformal, which is then treated with sodium polysulfide to obtain the finished product. See Chemical Formulas for the structure of liquid thiokol.
The proportion for liquid thiokol to perchlorate is usually 20-40% thiokol to 60-80% perchlorate. There are six types of thiokol liquid polymer (LP): LP-2, LP-3, LP-31, LP-32, LP-33, and LP-8. According to Urbanski, the difference in the polymers lies in the degree of polymerization or cross-linking. Curing the thiokol polymers is done with a special curing compound, composition C, for 24 hours at 80oF, then pressed for 10 minutes at 287-310oF.. Proportions for LP to C is 100 parts LP to 10-15 parts C.
The table for the liquid polymers is in parts by weight. The table for composition C is in percent.
Thiokol Chemical Corp. | Thiokol Chemical Corp. | Thiokol Chemical Corp. | Thiokol Chemical Corp. | |
name | LP-31 | LP-2 | LP-32 | Composition C |
Thiokol LP | 100 | 100 | 100 | |
Lead peroxide | 50 | |||
Sulfur | 0.15 | 0.1 | ||
Carbon black | 30 | 30 | ||
Stearic acid | 1 | 1 | 1 | 5 |
Dibutyl phthalate | 45 | |||
Soot (or zinc sulfide or lithopone) | 30-50 |
NOTE: Whistle rockets must be made in the same way as a standard firework whistle, in the sense that it must be pressed very firmly for it to produce a whistling effect. The catalyst can be any metal oxide, though the usual ones used are titanium dioxide, copper oxychloride, and red iron oxide.
DANGER: Whistle compositions should NEVER be rammed. They must be pressed or an explosion may result.
Vhryens | Barr | Steinberg | Steinberg | Best AFN 3 | |
Potassium perchlorate | 64 | 64 | 73 | 70 | 76 |
Sodium benzoate | 32 | 26 | 30 | ||
Sodium salicylate | 32 | 23 | |||
Catalyst | 1 | 1 | 1 | +1 | 1 |
Petroleum jelly | 3 | 3 | +2.5 | +5 | +3 |
NOTE: Strobe rockets function similar to strobe stars in that the reaction oscillates between flash and smoulder phase. The first formula given to me by John Steinberg can have the barium sulfate replaced with various other metal sulfates to obtain different colors.
DANGER: Copper sulfate can not be used in the first formula to produce a blue strobe. Copper sulfate absorbs moisture readily from the surrounding atmosphere. This moisture would then cause the magnesium and ammonium perchlorate to react producing heat, and eventually spontaneous combustion.
Barr | Burdick | |
Ammonium perchlorate | 60 | 63 |
Barium sulfate | 15 | |
Black copper oxide | 10 | |
GE Silicone II | 22 | |
PVC | 5 | |
Magnalium, -200 mesh | 23.5 | |
Magnesium, 100 mesh, flake | 1.5 | |
Potassium dichromate | +5 | |
solvent | 10% NC lacquer | not needed |
NOTE: The zinc/sulfur mixture is not a very efficient propellant due to its low specific impulse. In addition, the relatively high density of zinc adds much weight to the rocket, further reducing the propellant's effectiveness.
Zinc/sulfur propellant | |
Zinc powder | 67.1 |
Sulfur | 32.9 |
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